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Internal Rotation, Quadrupole Coupling, and Structure of (CH3)3SiCl Studied by Microwave Spectroscopy and ab Initio Calculation

✍ Scribed by I Merke; W Stahl; S Kassi; D Petitprez; G Wlodarczak

Publisher
Elsevier Science
Year
2002
Tongue
English
Weight
334 KB
Volume
216
Category
Article
ISSN
0022-2852

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✦ Synopsis

The microwave spectrum of (CH 3 ) 3 SiCl and its isotopic species (CH 3 ) 3 Si 37 Cl, (CH 3 ) 3 29 SiCl, (CH 3 ) 3 30 SiCl, and ( 13 CH 3 )(CH 3 ) 2 SiCl has been studied in the frequency range of 3 to 40 GHz. The barrier to internal rotation, the chlorine quadrupole coupling, and the structure were determined. Ab initio calculation were compared with the experimental results.

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