The influence of rhe Coriolis coupling on the angular autocorreln tion functions (ACF's) of symmetric-top molecules is alculnted startins with the nngulnr ACF's @en by St. Pierre and Stcelc. As on csnmple the theoretical ACF of the ~4 transition of CHCl3 is compared with the experiment. Ln 1969 St.
β¦ LIBER β¦
Internal rotation and Coriolis coupling in symmetric top molecules
β Scribed by Victor W. Laurie
- Publisher
- Elsevier Science
- Year
- 1964
- Tongue
- English
- Weight
- 329 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
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## 2. Memory functions Let us consider a polar fiuid in equifibriom. where each molecule is isolated from the others <free ratation hypothesis). In this case. for ~nmctric role\_ the autocorrelation function OFT of rhe mokcilar dipole moment is well known I&9]. If motion is classically described,