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Angular correlation functions of symmetric-top molecules influenced by coriolis coupling

✍ Scribed by K. Müller; F. Kneubühl

Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
162 KB
Volume
23
Category
Article
ISSN
0009-2614

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✦ Synopsis

The influence of rhe Coriolis coupling on the angular autocorreln tion functions (ACF's) of symmetric-top molecules is alculnted startins with the nngulnr ACF's @en by St. Pierre and Stcelc. As on csnmple the theoretical ACF of the ~4 transition of CHCl3 is compared with the experiment. Ln 1969 St. Pierre and Steele [I] calculated the angular autocorrelation Functions (ACF'S) of symmetric-top molecules for weak interactions by solving the corresponding potential-free Liouville equation.

📜 SIMILAR VOLUMES

Angular correlation functions of spheric
Angular correlation functions of spherical-top carbonyl complexes in gaseous N2 influenced by coriolis coupling
✍ K. Müller; P. Etique; F. Kneubühl 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 210 KB

The Fourier transform of measured line shapes of the triply degencratc vibrations of carbonyl complexes in gaseous N2 shows srrong devialions from rhe angular correlation functions calcuhted by Steele for the rigid sphericzdtop molecules. These deviations are explained theoretically with rhe aid of