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Angular correlation functions of spherical-top carbonyl complexes in gaseous N2 influenced by coriolis coupling

✍ Scribed by K. Müller; P. Etique; F. Kneubühl

Publisher: Elsevier Science
Year: 1973
Tongue: English
Weight: 210 KB
Volume: 23
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(73)89008-6

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✦ Synopsis

The Fourier transform of measured line shapes of the triply degencratc vibrations of carbonyl complexes in gaseous N2 shows srrong devialions from rhe angular correlation functions calcuhted by Steele for the rigid sphericzdtop molecules. These deviations are explained theoretically with rhe aid of Coriolis coupling and vibrational relaxation. For molecules in the gas phase it is possible LO separate the Coriolis coupling from the vibrational relaxation.

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Angular correlation functions of symmetr

Angular correlation functions of symmetric-top molecules influenced by coriolis coupling

✍ K. Müller; F. Kneubühl 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 162 KB

The influence of rhe Coriolis coupling on the angular autocorreln tion functions (ACF's) of symmetric-top molecules is alculnted startins with the nngulnr ACF's @en by St. Pierre and Stcelc. As on csnmple the theoretical ACF of the ~4 transition of CHCl3 is compared with the experiment. Ln 1969 St.