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Internal reactions in the Grignard-complex containing compounds with alkoxy-groups part III: Allyl phenyl ether

✍ Scribed by C. Blomberg; A. D. Vreugdenhil; P. Vink


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
404 KB
Volume
84
Category
Article
ISSN
0165-0513

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Internal reactions in the Grignard-compl
✍ C. Blomberg; A. D. Vreugdenhil; T. J. Homsma 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 270 KB

## Abstract If one molar equivalent of 2‐methyl‐, 2‐ethyl‐ or 2‐__n__‐propyl‐1,3‐dioxolane is used for the preparation of Grignard‐reagents in benzene, the five‐membered hetero‐ring is opened with formation of a magnesium halide 2‐alkoxyethan‐1‐olate. The steric and electronic effects of the alkyl