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Intermolecular reaction of an aryl nitrene

โœ Scribed by Odum, Robert A.; Aaronson, Alan M.


Book ID
121374124
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
270 KB
Volume
91
Category
Article
ISSN
0002-7863

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Insertion reactions of aryl nitrenes
โœ J.Herbert Hall; James W. Hill; Hu-chu Tsai ๐Ÿ“‚ Article ๐Ÿ“… 1965 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

Decomposition of phenyl azlde In hydrocarbon solvents Is known to give aniline, azobenzene, and polymeric material as the main products. It has now been found that N-alkylanllines are also formed In this reaction. For example, when phenyl azlde is decomposed In cyclohexane at 18O"C, N-cyclohexylanll