Triplet m-nitrophenyl nitrene reacts with frozen polycrystalline toluene at the benzylic position to give appreciable yields of a formal CH insertion adduct. This reaction does not occur on photolysis of m-nitrophenyl azide in toluene solution. Photoaffinity labelling (PAL) is a widely used techniqu
โฆ LIBER โฆ
Insertion reactions of aryl nitrenes
โ Scribed by J.Herbert Hall; James W. Hill; Hu-chu Tsai
- Book ID
- 104223321
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 200 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
โฆ Synopsis
Decomposition of phenyl azlde In hydrocarbon solvents Is known to give aniline, azobenzene, and polymeric material as the main products. It has now been found that N-alkylanllines are also formed In this reaction. For example, when phenyl azlde is decomposed In cyclohexane at 18O"C, N-cyclohexylanlline Is produced in low yield (82).
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