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Intermolecular Oxidative Amination of Olefins with Amines Catalyzed by the Pd(II)/NPMoV/O 2 System

โœ Scribed by Obora, Yasushi; Shimizu, Yosuke; Ishii, Yasutaka


Book ID
120595934
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
233 KB
Volume
11
Category
Article
ISSN
1523-7060

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Selective Wacker-type oxidation of termi
โœ Takahiro Yokota; Aki Sakakura; Masayuki Tani; Satoshi Sakaguchi; Yasutaka Ishii ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 117 KB

Selective Wacker-type oxidation of long-chain terminal alkenes to methylketones was successfully achieved by using Pd(OAc) 2 /molybdovanadophosphate (NPMoV)/O 2 system. The selectivity of the reaction increased by slow addition of the alkenes to the catalytic solution. The oxidation of a,v-dienes wa