## Abstract **Die direkte Umwandlung** einer terminalen Alkinfunktion in einen β‐Methoxyacrylat‐Rest gelingt mithilfe eines Bisoxazolin(box)‐Liganden. Acetyl‐ und Ketal‐Schutzgruppen werden unter den Reaktionsbedingungen ebenso wenig angegriffen wie freie Hydroxygruppen und säureempfindliche glycos
Intermolecular Methoxycarbonylation of Terminal Alkynes Catalyzed by Palladium(II) Bis(oxazoline) Complexes
✍ Scribed by Keisuke Kato; Satoshi Motodate; Tomoyuki Mochida; Takuya Kobayashi; Hiroyuki Akita
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 284 KB
- Volume
- 48
- Category
- Article
- ISSN
- 0044-8249
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## Abstract We report herein the synthesis of novel chiral S,N‐heterobidentate thiourea‐oxazoline ligands and their application to palladium‐catalyzed enantioselective bis(methoxycarbonylation)s of terminal olefins under mild conditions. Copper salts were found to play multiple roles in this reacti