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Intermolecular ligand exchange in tetranuclear metal carbonyl complexes

โœ Scribed by H.E. Hosseini; J.F. Nixon

Book ID
108351539
Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
174 KB
Volume
97
Category
Article
ISSN
0022-328X

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โœ Gerard R. Dobson; Ahmad Moradi-Araghi ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 638 KB

The kinetics and mechanism of the reaction of (tmen)W(CO), (tmen = N,N,N',N'-tetramethylethylenediamine) and (tmpa)W(COj4 (tmpa = N,N,N', N'-tetramethyl-1,3diaminopropane) with phosphines and phosphites (L) to afford L,W(CO), products have been investigated in detail. For both substrates, rate data