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Exchange interactions in tetranuclear copper(II) complexes

✍ Scribed by W. Haase

Book ID
104137773
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
106 KB
Volume
79
Category
Article
ISSN
0020-1693

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Tetranuclear copper(II) complexes. Coppe
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Reaction of copper(lll ions with the Schiff bases derived from histamine and salicylaldehyde or 2pyridinecarbaldehyde were investigated in acidic and basic media. The copper complexes obtained from the reactions in acidic solutions were mononuclear complexes I and II, while those from the reactions

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## Abstract Monocrystals and powders of some binuclear Cu(II) carboxilates which EPR spectra cannot be described by the usual __S__ = 1 spin Hamiltonian were investigated. It is shown that all the peculiarities of their spectra can be interpreted taking temperature dependent intermolecular exchange