Exchange interactions in tetranuclear copper(ii) complexes
β Scribed by W. Haase
- Book ID
- 103691963
- Publisher
- Elsevier Science
- Year
- 1984
- Weight
- 597 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0304-5102
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Reaction of copper(lll ions with the Schiff bases derived from histamine and salicylaldehyde or 2pyridinecarbaldehyde were investigated in acidic and basic media. The copper complexes obtained from the reactions in acidic solutions were mononuclear complexes I and II, while those from the reactions
## Abstract Monocrystals and powders of some binuclear Cu(II) carboxilates which EPR spectra cannot be described by the usual __S__ = 1 spin Hamiltonian were investigated. It is shown that all the peculiarities of their spectra can be interpreted taking temperature dependent intermolecular exchange