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Intermolecular effects on spin–spin coupling and magnetic shielding constants in gaseous difluoromethane

✍ Scribed by Marek Kubiszewski; Włodzimierz Makulski; Karol Jackowski


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
113 KB
Volume
704
Category
Article
ISSN
0022-2860

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1H, 13C and 19F nuclear magnetic shieldi
✍ M. Kubiszewski; W. Makulski; K. Jackowski 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 116 KB

Trifluoromethane (CHF 3 ) has been studied using 1 H, 13 C and 19 F NMR spectra in the gas phase at 300 K. For the first time all the spin-spin couplings and 13 C shielding of CHF 3 were measured as functions of density. After extrapolation to the zero-density limit the appropriate shielding ( 1 H,