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Intermolecular Double Prins-Type Cyclization: A Facile and Efficient Synthesis of 1,6-Dioxecanes

✍ Scribed by Punna Reddy Ullapu; Sun-Joon Min; Satish N. Chavre; Hyunah Choo; Jae Kyun Lee; Ae Nim Pae; Youseung Kim; Moon Ho Chang; Yong Seo Cho

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
360 KB
Volume
48
Category
Article
ISSN
0044-8249

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Intermolecular Double Prins-Type Cycliza
Intermolecular Double Prins-Type Cyclization: A Facile and Efficient Synthesis of 1,6-Dioxecanes
✍ Punna Reddy Ullapu; Sun-Joon Min; Satish N. Chavre; Hyunah Choo; Jae Kyun Lee; A 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB 👁 1 views

## Abstract **Verdoppelter Einsatz**: Die Titelreaktion überführt eine Reihe aromatischer Aldehyde in 26–85 % Ausbeute mithilfe von Allenylmethyl‐/Allylsilanen in 1,6‐Dioxecan‐Derivate (siehe Schema; Ar=Aryl, Tf=Triflat, THF=Tetrahydrofuran, TMS=Trimethylsilyl). Die Bisdien‐Produkte wurden durch Di