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Intermolecular (4+3) cycloadditions of aziridinyl enolsilanes

✍ Scribed by Lam, Sze Kui; Lam, Sarah; Wong, Wing-Tak; Chiu, Pauline


Book ID
121423663
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
491 KB
Volume
50
Category
Article
ISSN
1359-7345

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Gold-catalyzed intermolecular [4C+3C] cy
✍ Benjamin W. Gung; Lauren N. Bailey; Josh Wonser πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 508 KB

In the presence of the N-heterocyclic carbene gold catalyst (NHC-AuIPr, 7), propargyl esters 1a-f and 13 undergo a [4C + 3C] cycloaddition reaction with cyclopentadiene and furan under mild conditions. The evidence suggests the formation of the seven-membered ring occurs by a direct cycloaddition pr