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Intermediates in the Formation of γ-Pyrones from Hexose Derivatives: A Simple Synthesis of Kojic Acid and Hydroxymaltol

✍ Scribed by Prof. Dr. F. W. Lichtenthaler; Dr. P. Heidel


Publisher
John Wiley and Sons
Year
1969
Tongue
English
Weight
253 KB
Volume
8
Category
Article
ISSN
0044-8249

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Synthesis and folding preferences of γ-a
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The stereoselective synthesis of a-cinnamyl y-amino acids and the corresponding oligopeptides is described. Detailed 1D and 2D NMR studies in pyridine-ds .show that the (0tR)-cinnamyl y-amino acid tetrapeptide adopts a reverse turn structure, while the (otS)-cinnamyl y-amino acid tetrapeptide adopts