Intermediate phases and products of thermal decomposition of the compound Tl2Pb[Cu(NO2)6]
✍ Scribed by B. Papánková; J. Kožíšek; R. Kniep; W. Blase; H. Langfelderová
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 421 KB
- Volume
- 210
- Category
- Article
- ISSN
- 0040-6031
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Ba 2 Cu(HCOO) 6 grown at room temperature crystallizes in space group P2 On heating, the following changes are observed: (1) a reversible, hysteretic, 5rstorder phase transition at about 40}903C; (2) partial decomposition at 1903C; and (3) an irreversible change at 2303C related to decomposition. W
A pulse radiolysis technique has been used to measure a rate constant of (6.6f 1.3) x lo-r2 cm3 molecule-' s-i for the association reaction between CF3C(0)02 radicals and NO2 at 295 K and one atmosphere total pressure of SF, diluent. A FAIR/ smog chamber system was used to study the thermal decompos