✦ LIBER ✦

Intermediacy of ion neutral complexes in the fragmentation of short-chain dialkyl sulfides

✍ Scribed by Filsak, G.; Budzikiewicz, H.

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 178 KB
Volume: 34
Category: Article
ISSN: 1076-5174
DOI: 10.1002/(sici)1096-9888(199906)34:6<601::aid-jms811>3.0.co;2-8

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✦ Synopsis

The main fragmentation processes after electron ionization of butyl methyl and butyl ethyl sulfides are rationalized by the intermediacy of the ion neutral complex [RSH • methylcyclopropane] Yž as demonstrated by extensive labeling and collision activation studies.

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