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Interesting stereoselectivity of intramolecular Diels-Alder reactions leading to 5-carbomethoxy yohimbine systems

✍ Scribed by John Leonard; Andrew B. Hague; Guido Harms; Martin F. Jones

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
288 KB
Volume
40
Category
Article
ISSN
0040-4039

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✦ Synopsis

5-Carboxy apoyohimbine ring systems have been prepared via intramolecular Diels-Alder reactions of systems that incorporate electron-deficient dienes and acylamide dienophiles. These mismatched systems cyclise efficiently with exo stereoselectivity.

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