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ChemInform Abstract: Intramolecular Diels—Alder Reactions of 3-(Tetrahydropyridinyl)indoles: Stereoselective Synthesis of Novel Pentacyclic Ring Systems.

✍ Scribed by P. GHARAGOZLOO; M. MIYAUCHI; B. BIRDSALL; N. J. M. BIRDSALL


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis


Intramolecular

Diels-Alder Reactions of 3-(Tetrahydropyridinyl)indoles:

Stereoselective Synthesis of Novel Pentacyclic Ring Systems.

-A strategy to synthesize new pentacyclic indole alkaloids is shown. Key step is an intramolecular Diels-Alder reaction and following acid-catalyzed [1,3]-hydrogen shift. Some molecules with known biological functions can be obtained. -(GHARAGOZLOO, P.; MIYAUCHI,


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