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Interconversion of stannylium ions in the C4H11Sn+system

✍ Scribed by D. V. Vrazhnov; T. A. Kochina; A. A. Alferova; I. S. Ignat’ev


Book ID
111461016
Publisher
Springer
Year
2011
Tongue
English
Weight
470 KB
Volume
81
Category
Article
ISSN
1070-3632

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Na 6 Sn 4 Se 11 ´22 H 2 O can be crystallised at ±8 °C as yellow-orange needles from the 1 : 2 H 2 O/CH 3 OH mother liquor of a superheated reaction mixture of NaOH(s), Sn and Se. The bicyclic [Sn 4 Se 11 ] 6± anion exhibits crystallographic C 2 symmetry and is composed of corner-bridged SnSe 4 tetr