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Interconversion of Bicyclo[2.2.1]hept-2-yne and 5-Bicyclo[2.1.1]hexylidenecarbene

✍ Scribed by Gilbert, John C.; Yin, Jiandong

Book ID
124076503
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
73 KB
Volume
71
Category
Article
ISSN
0022-3263

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Swrmary: A new and highly stereoselective palladium-catalyzed synthesis is reported, based on two subsequent insertions of the bicycloE.2.gheptene system into an aryl or vinylpalladium bond, formed in situ from aryl or vinyl bromides. Recent papers on the synthesis of prostaglandin endoperoxide ana