Interconversion of 2-exo- and 2-endo-norbornyl oxocarbonium ions via the norbornyl cation. The free-enthalpy diagram
✍ Scribed by H. Hogeveen; C.F. Roobeek
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 118 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The effect of substituents at C4, 5, 6 and 7 on solvolysis rates and products of 2-exo-and 2-endo-norbornyl tosylates confirms that differential carbon participation is responsible for varying exo/endo rate and product ratios.
## Abstract The solvolysis rates and products of the 6‐__exo__‐substituted 2‐__exo__‐ **1a**‐**1u**, and 2‐__endo__‐norbornyl __p__‐toluenesulfonates **2a**‐**2u**, have been determined. In general, the rate constants for **1** and **2** (log __k__) correlate well with the inductive constants σ of
The large difference between the reaction constants p, for the solvolysis of the 6-exo-and 7-anti-substituted norbornyl tosylates 3 and 1, respectively, is further proof for the hypothesis that 2-norbornyl cations are anisotropic with regard to the transmission of polar effects and that through spac
## Abstract The solvolysis rate constants __k__ for the 6‐__endo__‐substituted 2‐__exo__‐norbornyl toluenesulfonates **7** have been determined. Values of log__k__ correlate well with the respective inductive constants of the substitutents except when the latter are nucleophilic and therefore lead
## Abstract The __exo__‐ and __endo__‐irontricarbonyl complexes of 5,6‐dimethylidene‐2‐__exo__‐norbornyl alcohols **10x, 10n**, __p__‐bromobenzenesulfonates **11x, 11n**, acetate **12x** and of the 2,3‐dimethylidene‐7‐__anti__‐norbornyl alcohols **17x, 17n**, __p__‐bromobenzenesulfonates **19x, 19n