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Interannular Communication in the Radical Anions of Bis-cyclooctatetraene Systems

✍ Scribed by Peters, Steven J.; Reiter, Richard C.; Stevenson, Cheryl D.


Book ID
127159380
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
121 KB
Volume
5
Category
Article
ISSN
1523-7060

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Cyclooctatetraene dianion from 1,5-cyclo
✍ Leslie H. Simons; J.J. Lagowski πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 58 KB

A novel synthesis of cyclooctatetraene dianion from 1,5-cyclooctadiene (1,5-COD) is described. The reaction of the potassium-naphthalene adduct with 1,5-COD proceeds at room temperature over 3 days in heptane/tetrahydrofuran to produce the target compound.