Interactions involving aromatic systems: Benzene + acetylene
✍ Scribed by Steve Scheiner; M. M. Szczȩśniak
- Publisher
- John Wiley and Sons
- Year
- 1984
- Tongue
- English
- Weight
- 770 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0020-7608
No coin nor oath required. For personal study only.
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A thorough knowledge of noncovalent interactions is crucial to the understanding of biological complexity. One of the less well understood but significant weak interactions in nature is the aromatic interaction. Recent studies have provided new insight into the driving force, stability and selectivi
## Abstract A one‐dimensional coordination polymer involving Tl ⋅⋅⋅ C interactions, [Tl(__μ__~4~‐dpa)]~__n__~(Hdpa = diphenylacetic acid), was synthesized and characterized. The single‐crystal X‐ray data of the compound show that the coordination number of the Tl^I^ ions is five and that Tl centers
To investigate sulfur-aromatic interactions, intermolecular interaction energies between dimethyl sulfide and benzene were computed using ab initio molecular orbital calculations. Inclusion of electron correlation at the MP2 level predicted significantly more stable complexes compared to Hartree-Foc