Interaction of the carbon—tin bond with beta positive charge

✍ Scribed by Joseph B. Lambert; Gen-Tai Wang

• Book ID: 104220047
• Publisher: Elsevier Science
• Year: 1988
• Tongue: French
• Weight: 210 KB
• Volume: 29
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)86109-2

✦ Synopsis

Participation of the C-Sn bond in the development of beta positive charge in aqueous trifluoroethanol does not depend on solvent nucleophilicity but does depend on Sn-C-c-x stereochemistry.

These observations favor a hyperconjugative interaction and predict a phenomenal acceleration in the antiperiplanar arrangement.