Interaction of the carbonβtin bond with
β
Joseph B. Lambert; Gen-Tai Wang
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Article
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1988
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Elsevier Science
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French
β 210 KB
## Participation of the C-Sn bond in the development of beta positive charge in aqueous trifluoroethanol does not depend on solvent nucleophilicity but does depend on Sn-C-c-x stereochemistry. These observations favor a hyperconjugative interaction and predict a phenomenal acceleration in the anti