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Interaction of P2S5–pyridine with enamines. Synthesis and reactions of l,6-trimethylene-5-cyano-2-mercapto-l,3,2-diazaphosphorine-2-thione

✍ Scribed by Dmitry B. Nilov; Alexander V. Kadushkin; Natalya P. Solov’eva; Andrey L. Sedov; Vladimir G. Granik


Book ID
111729859
Publisher
Royal Society of Chemistry
Year
1996
Tongue
English
Weight
183 KB
Volume
6
Category
Article
ISSN
0959-9436

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ChemInform Abstract: Interaction of P2S5
✍ D. B. NILOV; A. V. KADUSHKIN; N. P. SOLOV'EVA; A. L. SEDOV; V. G. GRANIK 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

Interaction of P2S5-Pyridine with Enamines. Synthesis and Reactions of 1,6-Trimethylene-5-cyano-2-mercapto-1,3,2-diazaphosphorine-2thione. -A new synthetic approach to the title diazaphosphorinethione (IV) based on the reaction of enamines such as (III) with P2S5/pyridine is presented. The obtained

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✍ E. Ager; B. Iddon; H. Suschitzky 📂 Article 📅 1969 🏛 Elsevier Science 🌐 French ⚖ 196 KB

In connection with other work it became necessary for us to prepare 2,3,6-trichloro-4-•ercaptopyridine (II). A sulphur atom in organosulphur compounds, such as thiophens (1) and benzo[&]thiophens (2), is known to be capable of complexing with n-butyl-lithium, and it seemed, therefore, ihat reaction