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Interaction of ligands with the metal centers of hydrogenases: An EPR study

✍ Scribed by D.S. Patil; S.H. He; T.V. Morgan; D.V. DerVartanian; H.D. Peck Jr.; J. LeGall; B.H. Huynh


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
65 KB
Volume
43
Category
Article
ISSN
0162-0134

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Single crystal EPR study of the Ni cente
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EPR spectra of single crystals of NiFe hydrogenase from Desulfovibrio vulgaris Miyazaki F were evaluated and yielded the g-tensors of the Ni center for two different states of the enzyme. The g-values associated with these states are identical to those measured in frozen solutions for the ready (Ni-