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The electronic g-tensor of the nickel-center in hydrogenase: A single crystal EPR study

✍ Scribed by Ch Geβner; O Trofanchuk; K Kawagoe; Y Higuchi; N Yasuoka; W Lubitz


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
70 KB
Volume
59
Category
Article
ISSN
0162-0134

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Single crystal EPR study of the Ni cente
✍ Ch. Geßner; O. Trofanchuk; K. Kawagoe; Y. Higuchi; N. Yasuoka; W. Lubitz 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 550 KB

EPR spectra of single crystals of NiFe hydrogenase from Desulfovibrio vulgaris Miyazaki F were evaluated and yielded the g-tensors of the Ni center for two different states of the enzyme. The g-values associated with these states are identical to those measured in frozen solutions for the ready (Ni-