Interaction of iron(II) phthalocyanine with molecular oxygen in concentrated sulfuric acid: kinetics and mechanism
β Scribed by Ercolani, C.; Monacelli, F.; Rossi, G.
- Book ID
- 126941165
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 677 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0020-1669
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Oxidation of the Fe n chelates [FeL l (L = phen or bipy) by Cr w and Mn TM in H2SO 4 medium was found to proceed through the formation of a bimetallic insertion complex which decomposes in the slow step, followed by electron transfer from [FeLl to the oxidant. The reactions are catalysed by both ani
In the hot gas desulfurization process using iron oxide sorbent. the regeneration of the sultided iron oxide sorbent consists of two reactions: the oxidation of iron sulfide with air, and its reaction with the sulfur dioxide formed during the air oxidation. This part describes the kinetic studies on