The oxidation of organic compounds with ruthenium tetroxide was first reported by Djerassi,' who oxidized sulfides to sulfoxides and sulfones, phenanthrene to phenanthraquinone, and found that ether, benzene, and pyridine are oxidized, whereas carbon tetrachloride, chloroform, alkanes, water, ketone
Interaction of hydrogen fluoride with ruthenium tetroxide
β Scribed by Sakurai Tsutomu; Takahashi Akira
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 35 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0022-1139
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The interaction of methanol with a clean <I 10) ruthenium surface has been studied using temperature programmed desorption methods. Methanol dissociates upon adsorption at 300 K and yields Ha(g) and chemisorbed CO as the domiwt products. Randomization of evolved hydrogen was shown to occur during me
The oxidation of low-rank coals with ruthenium tetroxide was investigated with the objective of elucidating the aliphatic bridging groups and hydroaromatic groups present in the organic structure. The reaction was carried out in a two-phase system with a phase transfer catalyst. An accurate quantita