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Interaction of chromium and tungsten carbonyls with diethyldithiocarbamate complexes of selenium(II) and tellurium(II). Synthesis and molecular and crystal structures of WSe2(S2CNEt2)3·0.5H2O and [W(S2CNEt2)4]2W6O19

✍ Scribed by V.P. Fedin; Yu.V. Mironov; A.V. Virovets; N.V. Podberezskaya; V.Ye. Fedorov


Book ID
108428666
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
464 KB
Volume
11
Category
Article
ISSN
0277-5387

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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure