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Interaction of carbanions with azobenzene and related compounds

✍ Scribed by Kaiser, Edwin M.; Bartling, Gregory J.

Book ID
126200976
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
690 KB
Volume
37
Category
Article
ISSN
0022-3263

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In 1970 we found perfluoro-tert.-butyl anion (CF3)3C-, generated from perfluoroisobutene (PFIB) and KF in dimethyl formami de medium to react easily with perfluoronitrosoalkanes'. According to general views on the polarization of the nitroso group and considering the nucleophilic attack being direc