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Nucleophilic Reactivities of Sulfur Ylides and Related Carbanions: Comparison with Structurally Related Organophosphorus Compounds

✍ Scribed by Roland Appel; Herbert Mayr


Book ID
101840024
Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
249 KB
Volume
16
Category
Article
ISSN
0947-6539

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Structural studies of carbanionic specie
✍ Tekla Bottin-Strzalko; Jacqueline Seyden-Penne; Marie-JosΓ© Pouet; Marie-Paule Si πŸ“‚ Article πŸ“… 1982 πŸ› John Wiley and Sons 🌐 English βš– 384 KB

## Abstract The structure of the carbanionic species 4 formed from diethyl(2‐oxopropyl)phosphonate and __t__‐BuOK has been studied by ^1^H, ^13^C and ^31^P NMR. In an associating medium (pyridine), a single chelated (C) carbanionic species 4__Z__ (C) is observed. Two slowly interconverting species