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Interaction of alkanes with unsaturated metal centers. 2. Complexes of alkanes and fluoroalkanes with tungsten pentacarbonyl in the gas phase

✍ Scribed by Brown, Carl E.; Ishikawa, Yoichi; Hackett, Peter A.; Rayner, David M.


Book ID
118137991
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
844 KB
Volume
112
Category
Article
ISSN
0002-7863

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Interaction of alkanes with unsaturated
✍ Yo-ichi Ishikawa; Carl E. Brown; Peter A. Hackett; David M. Rayner πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 460 KB

The complex W( CO)&H6 has been observed in the gas phase by time-resolved infrared spectroscopy following 308 nm laser photolysis of W(CO), in the presence of C,H6. The complex is shown to be in equilibrium with its precursor, W(CO),, at room temperature and to have a C2Hb binding energy of 9.7 zh 3