✦ LIBER ✦

Interaction of alkanes with unsaturated metal centres: The complex W(CO)5C2H6 in the gas phase

✍ Scribed by Yo-ichi Ishikawa; Carl E. Brown; Peter A. Hackett; David M. Rayner

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 460 KB
Volume: 150
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87238-5

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✦ Synopsis

The complex W( CO)&H6 has been observed in the gas phase by time-resolved infrared spectroscopy following 308 nm laser photolysis of W(CO), in the presence of C,H6. The complex is shown to be in equilibrium with its precursor, W(CO),, at room temperature and to have a C2Hb binding energy of 9.7 zh 3 kcal mol-'.

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