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Interaction of 2-methyl-2,5-dioxo-1,2-oxaphospholane with trimethylsilyl cyanide

✍ Scribed by I. L. Odinets; E. A. Antonov; P. V. Petrovsky; Yu. I. Morozik; Yu. A. Krivolapov; B. I. Freger; V. Ya. Starkov; T. A. Mastryukova; M. I. Kabachnik

Book ID
112387614
Publisher
Springer
Year
1993
Tongue
English
Weight
934 KB
Volume
42
Category
Article
ISSN
1573-9171

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πŸ“œ SIMILAR VOLUMES

Stereochemistry of 1,2-Oxaphospholanes,
Stereochemistry of 1,2-Oxaphospholanes, VIII. Synthesis, Stereochemistry, and Ring Opening Reactions of Diastereomeric 3-Hydroxy-2-methoxy-5-methyl-1,2-oxaphospholan-2-ones
✍ WrΓ³blewski, Andrzej E. πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 511 KB

Addition of dimethyl phosphonate to acetaldol gives a 3 : 7 mixture of diastereomeric dimethyl (1,3-dihydroxybutyl)phosphonates 3 and 4. The relative configurations at C-I and C-3 in these diols were established by the 13C NMR data of their 0-benzylidene derivatives. Axial preference-for the dimetho