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Reactions of 2-oxo-2-dialkylamino-1,2-oxaphospholanes with acid chlorides

✍ Scribed by O. N. Nuretdinova; F. F. Guseva

Book ID
112449500
Publisher
Springer
Year
1990
Tongue
English
Weight
138 KB
Volume
39
Category
Article
ISSN
1573-9171

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✍ WrΓ³blewski, Andrzej E. πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 511 KB

Addition of dimethyl phosphonate to acetaldol gives a 3 : 7 mixture of diastereomeric dimethyl (1,3-dihydroxybutyl)phosphonates 3 and 4. The relative configurations at C-I and C-3 in these diols were established by the 13C NMR data of their 0-benzylidene derivatives. Axial preference-for the dimetho