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Interaction between the benzyl radical and the chloride anion in rigid matrices

✍ Scribed by Masahiro Irie; Masaaki Shimizu; Hiroshi Yoshida

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 326 KB
Volume: 25
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)80342-8

No coin nor oath required. For personal study only.

✦ Synopsis

The benzyl radical was formed by the photolysis and r-irradiation of organic rigid matrices (hydrocarbons, 2methyltetrahydrofuran and ethanol) containing benzyl chloride, and its electronic spectra were examined by a fluorescence spectrometer.

It is shown that the spectra are modified by a chloride anion situated close to a benzyl radical. when it was formed through dissociative electron attachment to benzyl chloride in the non-polar matrix.

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