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Inter- and intramolecular hydrogen bonds – Structures of 1-methylpyrrole-2-carboxamide and 1-hydroxypyrrole-2-carboxamide

✍ Scribed by Sławomir J. Grabowski; Marcin Palusiak; Alina T. Dubis; Arno Pfitzner; Manfred Zabel


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
427 KB
Volume
844-845
Category
Article
ISSN
0022-2860

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Two conformational pseudo-polymorphs of m-di-(pyrrole-2-carboxamide)-xylylene, anhydrous form-crystal I and 0.5 EtOAc solvate-crystal II, were obtained and characterized by X-ray crystallography. Two hydrogen bonding motifs of pyrrolic amide, having graph-set notation R 1 2 ð7Þ were observed. The en