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Insight into the rotational motion of in Si from the IR spectrum of HD

✍ Scribed by M. Stavola; G. Alvin Shi; W. Beall Fowler; E. Elinor Chen

Publisher: Elsevier Science
Year: 2006
Tongue: English
Weight: 157 KB
Volume: 376-377
Category: Article
ISSN: 0921-4526
DOI: 10.1016/j.physb.2005.12.010

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✦ Synopsis

The rotational-vibrational transitions of HD in Si are subject to less restrictive selection rules than for the homonuclear H 2 and D 2 molecules and give rise to a richer IR spectrum. IR lines for transitions between rotational-vibrational states of the interstitial HD molecule with rotational quantum numbers J ¼ 0, 1, and 2 have been observed. The assignment of the rotational-vibrational spectrum of interstitial HD, with additional transitions that occur for HD but not for H 2 or D 2 , is confirmed by uniaxial stress results.

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