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Inner-shell excitation of gas phase carbonates and α,γ-dicarbonyl compounds

✍ Scribed by Robert Lessard; Jérôme Cuny; Glyn Cooper; Adam P. Hitchcock


Book ID
108088871
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
500 KB
Volume
331
Category
Article
ISSN
0301-0104

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Formal gas-phase polar [4 + 1+] cycloadd
✍ Eduardo C. Meurer; Liliane G. Cabrini; Fabio C. Gozzo; Marcos N. Eberlin 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 145 KB

## Abstract Ion/molecule reactions of ^+^CH~2~ OCH~2~^·^ with α‐dicarbonyl compounds were performed via pentaquadrupole mass spectrometry. Besides the previously known [3^+^ + 2] 1,3‐cycloaddition reaction that forms cyclic 1,3‐dioxonium ions, an unprecedented reaction proceeding formally by [4 + 1