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Initiation of butadiene popcorn polymerization

✍ Scribed by Miller, G. H. ;Eliason, R. R. ;Pritchard, G. O.

Publisher
Wiley (John Wiley & Sons)
Year
2007
Weight
427 KB
Volume
4
Category
Article
ISSN
0449-2994

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water is usually recognized as a strong inhibitor of transition-metal polymerization. By analyzing the addition order effect of the ingredients, we show that the reduction of cobalt in the presence of butadiene is necessary for the polymerization. Radical-polymerization inhibitors such as phenols di