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Inhibitory action of (4S,6S,7R)-isomer to pheromonal activity of serricornin, (4S,6S,7S)-7-Hydroxy-4,6-dimethyl-3-nonanone

✍ Scribed by M. Mori; K. Mochizuki; M. Kohno; T. Chuman; A. Ohnishi; H. Watanabe; K. Mori


Book ID
105047625
Publisher
Springer
Year
1986
Tongue
English
Weight
457 KB
Volume
12
Category
Article
ISSN
0098-0331

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Eine kurze synthese von serricornin, (4S
✍ Hartmut Redlich; Karsten Samm; Jan-Bernd Lenfers; Wilfried Bruns πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 535 KB

Starting from D-glucose, a novel sequence of the syntheses leading to (3S,5S,6S)-6-ethyl-3,5-dimethyltetrahydro-2H-pyran-2-one (4) is described. Key steps are the hydrogenation of 3,5,6-trideoxy-l,2-O-isopropylidene-3-C-methyl-cr-D-glycero-hex-3,5-dienose leading to 3,5,6-trideoxy-1,2-O-isopropylide