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Inhibition of the oxidation of carbon-carbon composites by bromination

✍ Scribed by C.T. Ho; D.D.L. chung


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
948 KB
Volume
28
Category
Article
ISSN
0008-6223

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✦ Synopsis


Bromination by exposure to bromine vapor at room temperature was effective for inhibiting the oxidation of carbon-carbon composites in the form of PAN-based carbon fibers impregnated with resin. which was subsequently carbonized at 1000 or 2000Β°C. The oxidation rate was decreased by up to 43%. In addition. electrical resistivity was decreased by up to 39% However. the tensile modulus was decreased by 16-1795 and tensile strength was decreased by 17-20s; the ductility was not affected. The increased oxidation resistance may be due to bromine adsorption or the electron transfer from graphite to bromine. The bromine resided in the matrix of the composite. particularly in pores within the matrix. Bromination was also attempted by the electrochemical method, but it resulted in negligible weight uptake in the carbon-carbon composite. Carbon-carbon composites that had been graphitized at 2700Β°C were damaged by bromination.


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