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Inhibition of Bond Exchange in Cyclooctatetraenes

✍ Scribed by Prof. D. Bryce-Smith; Dr. A. Gilbert; J. Grzonka


Publisher
John Wiley and Sons
Year
1971
Tongue
English
Weight
252 KB
Volume
10
Category
Article
ISSN
0044-8249

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## Abstract The present study of the cyclooctatetraene potential energy surface shows the presence of a bifurcation (valley ridge inflection point) in the intrinsic reaction coordinate path between the two transition states of D~8h~ and D~4h~ symmetries. This result is of capital importance for the