✦ LIBER ✦
Bond fixation in annulenes. 7. Direct resolution of chiral cyclooctatetraenes
✍ Scribed by John M. Gardlik; Leo A. Paquette
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- French
- Weight
- 214 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Cycloaddition of an optically pure triazolinedione to a racemic cyclooctatetraene, followed by separation of the resulting diastereomers and hydrolysis-oxidation, delivers the polyolefin in high enantiomeric purity.