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Infrared spectrum of nitrosyltricarbonylcobalt in the solid state

โœ Scribed by R. Cataliotti; G. Paliani; A. Poletti

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
373 KB
Volume
11
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The infrared spectrum of crystalline nitrosyltricarbonylcobalt has b&n measured at different temperatures between 4OCO and 300 cm-' . Spectroscopic evidence shows that the form stable between the melting point and 248% has the same degree of disorder as the Iiquid. In the ordered form the uystaIs sizm to be mor~~cIinic, belonging to the C& space grdup. Assnming a CS site symmetr& and a C,n unit ceII symmetry the observed effects for the .ordered f&m I&w. been VeII interpreted.

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