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Infrared Spectrum of Cyanogen Iodide (ICN)

✍ Scribed by G. Thompson; A.G. Maki

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 520 KB
Volume: 160
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1993.1158

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✦ Synopsis

The high-resolution infrared spectrum of (\mathrm{ICN}) has been studied from 460 to (2700 \mathrm{~cm}^{-1}) with a Fourier transform spectrometer. The band origins and rotational and centrifugal distortion constants have been determined for the (10^{\circ} 0-00^{\circ} 0,11^{1} 0-01^{1} 0,20^{\circ} 0-10^{\circ} 0,02^{\circ} 0-00^{\circ} 0,03^{1} 0-) (01^{1} 0,04^{\circ} 0-02^{2} 0,01^{1} 1-00^{\circ} 0), and (10^{\circ} 1-00^{\circ} 0) bands. All of the energy levels below (900 \mathrm{~cm}^{-1}) and most of the anharmonic vibrational constants for this molecule have now been determined. Also, the dependence of the Fermi resonance on (\boldsymbol{v}_{2}) has been determined. (c) 1993 Academic Press, Inc.

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